Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance

Cai Jian-guo; Shi Hong-yan; Zhu Zhi-rong; Shi Xiao-li

doi:doi:10.11648/j.sd.20160402.23

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Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance

Cai Jian-guo, Shi Hong-yan, Zhu Zhi-rong, Shi Xiao-li

Published in Science Discovery (Volume 4, Issue 2)

Received: 19 May 2016 Published: 19 May 2016

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Abstract

With nano-alumina modified by the fat acid as an inorganic template for making pores, a new kind of porous resin particle with the large surface was synthesized by emulsion polymerization. Moreover, the sulfonated polystyrene resin was fluorinated to increase its acid strength up to Ho 8.6 and the acid amount of 4.1mmol/g. The ratio of butane to water was increased by packing the catalytic resin with the fixed beds of four stages. Under reaction temperature of 168-174°C, butane to water ratio of 2 mol/mol and WHSV1.0 h-1, hydration reaction conversion was over 15 wt%, with the butyl alcohol selectivity of 99 wt% and a good thermal stability.

Published in	Science Discovery (Volume 4, Issue 2)
DOI	10.11648/j.sd.20160402.23
Page(s)	137-141
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2016. Published by Science Publishing Group

Keywords

Butene Hydration, Pores, Acid Resin, Catalyst, Reaction Performance

References

[1]	崔锡红,曾群英,李吉辉,赵光辉,混合碳四中丁烯-1的分离技术及综合利用[J],2011,11:33-37。
[2]	朱青芳.甲乙酮的合成方法及生产消费情况. 医药化工[J],2007(3):33–37。
[3]	何英华，王苑，杨玉和,等。C4烃资源综合利用技术进展[J],化工技术与开发，2012,41(3):28-34。
[4]	高会元，国内外甲乙酮生产工艺技术进展[J],化工进展，2001,20(11):31-34。
[5]	李亚军,华贲,李国庆.我国液化石油气资源的优化利用[J].石油炼制与化工,2005,36(3):46-5O。
[6]	王国强，碳四烃综合利用研究[J],中国石油和化工标准与质量,2014(10):16-17。
[7]	董炳利，周金波，王燕飞，等.碳四烃中异丁烯水合制叔丁醇技术进展[J]，应用化工，2012,41(4):693-696。
[8]	Kharitonov A P，Kharitonov L N，TaegeR.Direct fluorination of polymer vessels and membranes: Enhancement of barrier and gas separation properties ［J］. ActualiteChimique，2006，301: 130－134.
[9]	Lagow R J，Margrave J L. The controlled reactionof hydrocarbon polymers with elemental fluorine ［J］.Polym Lett，1974，12: 177-184.
[10]	王金明,刘文飞,氟化树脂催化异丁烯水合反应研究[J],化学工业与工程,2010,27:214-218。

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APA Style

Cai Jian-guo, Shi Hong-yan, Zhu Zhi-rong, Shi Xiao-li. (2016). Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance. Science Discovery, 4(2), 137-141. https://doi.org/10.11648/j.sd.20160402.23

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ACS Style

Cai Jian-guo; Shi Hong-yan; Zhu Zhi-rong; Shi Xiao-li. Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance. Sci. Discov. 2016, 4(2), 137-141. doi: 10.11648/j.sd.20160402.23

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AMA Style

Cai Jian-guo, Shi Hong-yan, Zhu Zhi-rong, Shi Xiao-li. Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance. Sci Discov. 2016;4(2):137-141. doi: 10.11648/j.sd.20160402.23

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@article{10.11648/j.sd.20160402.23,
  author = {Cai Jian-guo and Shi Hong-yan and Zhu Zhi-rong and Shi Xiao-li},
  title = {Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance},
  journal = {Science Discovery},
  volume = {4},
  number = {2},
  pages = {137-141},
  doi = {10.11648/j.sd.20160402.23},
  url = {https://doi.org/10.11648/j.sd.20160402.23},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20160402.23},
  abstract = {With nano-alumina modified by the fat acid as an inorganic template for making pores, a new kind of porous resin particle with the large surface was synthesized by emulsion polymerization. Moreover, the sulfonated polystyrene resin was fluorinated to increase its acid strength up to Ho 8.6 and the acid amount of 4.1mmol/g. The ratio of butane to water was increased by packing the catalytic resin with the fixed beds of four stages. Under reaction temperature of 168-174°C, butane to water ratio of 2 mol/mol and WHSV1.0 h-1, hydration reaction conversion was over 15 wt%, with the butyl alcohol selectivity of 99 wt% and a good thermal stability.},
 year = {2016}
}

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TY  - JOUR
T1  - Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance
AU  - Cai Jian-guo
AU  - Shi Hong-yan
AU  - Zhu Zhi-rong
AU  - Shi Xiao-li
Y1  - 2016/05/19
PY  - 2016
N1  - https://doi.org/10.11648/j.sd.20160402.23
DO  - 10.11648/j.sd.20160402.23
T2  - Science Discovery
JF  - Science Discovery
JO  - Science Discovery
SP  - 137
EP  - 141
PB  - Science Publishing Group
SN  - 2331-0650
UR  - https://doi.org/10.11648/j.sd.20160402.23
AB  - With nano-alumina modified by the fat acid as an inorganic template for making pores, a new kind of porous resin particle with the large surface was synthesized by emulsion polymerization. Moreover, the sulfonated polystyrene resin was fluorinated to increase its acid strength up to Ho 8.6 and the acid amount of 4.1mmol/g. The ratio of butane to water was increased by packing the catalytic resin with the fixed beds of four stages. Under reaction temperature of 168-174°C, butane to water ratio of 2 mol/mol and WHSV1.0 h-1, hydration reaction conversion was over 15 wt%, with the butyl alcohol selectivity of 99 wt% and a good thermal stability.
VL  - 4
IS  - 2
ER  -

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Author Information

Cai Jian-guo

Jiangsu Hyper Functional Materials Co. Ltd., Suzhou, China
Shi Hong-yan

Jiangsu Hyper Functional Materials Co. Ltd., Suzhou, China
Zhu Zhi-rong

Jiangsu Hyper Functional Materials Co. Ltd., Suzhou, China
Shi Xiao-li

Jiangsu Hyper Functional Materials Co. Ltd., Suzhou, China

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Plain Text BibTeX RIS

APA Style

Cai Jian-guo, Shi Hong-yan, Zhu Zhi-rong, Shi Xiao-li. (2016). Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance. Science Discovery, 4(2), 137-141. https://doi.org/10.11648/j.sd.20160402.23

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ACS Style

Cai Jian-guo; Shi Hong-yan; Zhu Zhi-rong; Shi Xiao-li. Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance. Sci. Discov. 2016, 4(2), 137-141. doi: 10.11648/j.sd.20160402.23

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AMA Style

Cai Jian-guo, Shi Hong-yan, Zhu Zhi-rong, Shi Xiao-li. Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance. Sci Discov. 2016;4(2):137-141. doi: 10.11648/j.sd.20160402.23

Copy | Download

@article{10.11648/j.sd.20160402.23,
  author = {Cai Jian-guo and Shi Hong-yan and Zhu Zhi-rong and Shi Xiao-li},
  title = {Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance},
  journal = {Science Discovery},
  volume = {4},
  number = {2},
  pages = {137-141},
  doi = {10.11648/j.sd.20160402.23},
  url = {https://doi.org/10.11648/j.sd.20160402.23},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20160402.23},
  abstract = {With nano-alumina modified by the fat acid as an inorganic template for making pores, a new kind of porous resin particle with the large surface was synthesized by emulsion polymerization. Moreover, the sulfonated polystyrene resin was fluorinated to increase its acid strength up to Ho 8.6 and the acid amount of 4.1mmol/g. The ratio of butane to water was increased by packing the catalytic resin with the fixed beds of four stages. Under reaction temperature of 168-174°C, butane to water ratio of 2 mol/mol and WHSV1.0 h-1, hydration reaction conversion was over 15 wt%, with the butyl alcohol selectivity of 99 wt% and a good thermal stability.},
 year = {2016}
}

Copy | Download

TY  - JOUR
T1  - Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance
AU  - Cai Jian-guo
AU  - Shi Hong-yan
AU  - Zhu Zhi-rong
AU  - Shi Xiao-li
Y1  - 2016/05/19
PY  - 2016
N1  - https://doi.org/10.11648/j.sd.20160402.23
DO  - 10.11648/j.sd.20160402.23
T2  - Science Discovery
JF  - Science Discovery
JO  - Science Discovery
SP  - 137
EP  - 141
PB  - Science Publishing Group
SN  - 2331-0650
UR  - https://doi.org/10.11648/j.sd.20160402.23
AB  - With nano-alumina modified by the fat acid as an inorganic template for making pores, a new kind of porous resin particle with the large surface was synthesized by emulsion polymerization. Moreover, the sulfonated polystyrene resin was fluorinated to increase its acid strength up to Ho 8.6 and the acid amount of 4.1mmol/g. The ratio of butane to water was increased by packing the catalytic resin with the fixed beds of four stages. Under reaction temperature of 168-174°C, butane to water ratio of 2 mol/mol and WHSV1.0 h-1, hydration reaction conversion was over 15 wt%, with the butyl alcohol selectivity of 99 wt% and a good thermal stability.
VL  - 4
IS  - 2
ER  -

Copy | Download