Synthesis, Surface Activities and Anti-Bacterial Activity of (Copper and Nickel) Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants

Ibrahim Abdelsalam Sabbah; Mostafa Eid Hendawy; Mohammed Fahmy Zaky; Nabel Abdelmonem Negm

doi:doi:10.11648/j.mc.20180602.13

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Synthesis, Surface Activities and Anti-Bacterial Activity of (Copper and Nickel) Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants

Ibrahim Abdelsalam Sabbah, Mostafa Eid Hendawy, Mohammed Fahmy Zaky, Nabel Abdelmonem Negm

Published in Modern Chemistry (Volume 6, Issue 2)

Received: 12 June 2018 Accepted: 25 June 2018 Published: 27 July 2018

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Abstract

A series of cationic polyurethane surfactant [PQ14, PQ16 and PQ18] were synthesized by the reaction of alkyl bromoacetate (namely: tetradecyl-, hexadecyl- and octadecyl bromoacetate) as quaternizing agents and modified polyurethane contains tertiary amine species. Modified polyurethane was prepared by the reaction of toluene diisocyanate (TDI) and Triethanol amine mono mercaptoacetate. Grinding method is used to synthesize copper and nickel nanoparticles which stabilized by Cationic Thiol polyurethane surfactants. The chemical structures of the prepared surfactants were confirmed using elemental analysis, FTIR, UV and ¹H-NMR spectroscopy. The molecular weight measurements of the prepared polymers showed that the segments of each polymer contain average 10 units of the urethane-Triethanol amine mercaptoacetate. The surface activities of the prepared surfactants including: surface tension (g), effectiveness (π_cmc), concentration at micelle formation (CMC), efficiency (Pc₂₀), maximum concentration at the interface (G_max), average area occupied by each surfactant molecule at the interface at equilibrium (A_min) of surfactants solutions were established at 25°C. The surface tension and the critical micelle concentration values of the prepared surfactants were gradually decreased by the gradual increase of their alkyl chain length. Antimicrobial activity of the synthesized cationic surfactants and their nanostructure with copper and nickel nanoparticles were evaluated against pathogenic bacteria and fungi. The antimicrobial activity showed the enhancement in the antimicrobial activity of the synthesized cationic surfactants in the nanostructures form.

Published in	Modern Chemistry (Volume 6, Issue 2)
DOI	10.11648/j.mc.20180602.13
Page(s)	23-34
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Cationic Surfactants, Micellization, Adsorption, Surface Properties, Polyurethane, Antimicrobial Activity

References

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APA Style

Ibrahim Abdelsalam Sabbah, Mostafa Eid Hendawy, Mohammed Fahmy Zaky, Nabel Abdelmonem Negm. (2018). Synthesis, Surface Activities and Anti-Bacterial Activity of (Copper and Nickel) Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants. Modern Chemistry, 6(2), 23-34. https://doi.org/10.11648/j.mc.20180602.13

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ACS Style

Ibrahim Abdelsalam Sabbah; Mostafa Eid Hendawy; Mohammed Fahmy Zaky; Nabel Abdelmonem Negm. Synthesis, Surface Activities and Anti-Bacterial Activity of (Copper and Nickel) Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants. Mod. Chem. 2018, 6(2), 23-34. doi: 10.11648/j.mc.20180602.13

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AMA Style

Ibrahim Abdelsalam Sabbah, Mostafa Eid Hendawy, Mohammed Fahmy Zaky, Nabel Abdelmonem Negm. Synthesis, Surface Activities and Anti-Bacterial Activity of (Copper and Nickel) Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants. Mod Chem. 2018;6(2):23-34. doi: 10.11648/j.mc.20180602.13

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@article{10.11648/j.mc.20180602.13,
  author = {Ibrahim Abdelsalam Sabbah and Mostafa Eid Hendawy and Mohammed Fahmy Zaky and Nabel Abdelmonem Negm},
  title = {Synthesis, Surface Activities and Anti-Bacterial Activity of (Copper and Nickel) Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants},
  journal = {Modern Chemistry},
  volume = {6},
  number = {2},
  pages = {23-34},
  doi = {10.11648/j.mc.20180602.13},
  url = {https://doi.org/10.11648/j.mc.20180602.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.mc.20180602.13},
  abstract = {A series of cationic polyurethane surfactant [PQ14, PQ16 and PQ18] were synthesized by the reaction of alkyl bromoacetate (namely: tetradecyl-, hexadecyl- and octadecyl bromoacetate) as quaternizing agents and modified polyurethane contains tertiary amine species. Modified polyurethane was prepared by the reaction of toluene diisocyanate (TDI) and Triethanol amine mono mercaptoacetate. Grinding method is used to synthesize copper and nickel nanoparticles which stabilized by Cationic Thiol polyurethane surfactants. The chemical structures of the prepared surfactants were confirmed using elemental analysis, FTIR, UV and 1H-NMR spectroscopy. The molecular weight measurements of the prepared polymers showed that the segments of each polymer contain average 10 units of the urethane-Triethanol amine mercaptoacetate. The surface activities of the prepared surfactants including: surface tension (g), effectiveness (πcmc), concentration at micelle formation (CMC), efficiency (Pc20), maximum concentration at the interface (Gmax), average area occupied by each surfactant molecule at the interface at equilibrium (Amin) of surfactants solutions were established at 25°C. The surface tension and the critical micelle concentration values of the prepared surfactants were gradually decreased by the gradual increase of their alkyl chain length. Antimicrobial activity of the synthesized cationic surfactants and their nanostructure with copper and nickel nanoparticles were evaluated against pathogenic bacteria and fungi. The antimicrobial activity showed the enhancement in the antimicrobial activity of the synthesized cationic surfactants in the nanostructures form.},
 year = {2018}
}

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TY  - JOUR
T1  - Synthesis, Surface Activities and Anti-Bacterial Activity of (Copper and Nickel) Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants
AU  - Ibrahim Abdelsalam Sabbah
AU  - Mostafa Eid Hendawy
AU  - Mohammed Fahmy Zaky
AU  - Nabel Abdelmonem Negm
Y1  - 2018/07/27
PY  - 2018
N1  - https://doi.org/10.11648/j.mc.20180602.13
DO  - 10.11648/j.mc.20180602.13
T2  - Modern Chemistry
JF  - Modern Chemistry
JO  - Modern Chemistry
SP  - 23
EP  - 34
PB  - Science Publishing Group
SN  - 2329-180X
UR  - https://doi.org/10.11648/j.mc.20180602.13
AB  - A series of cationic polyurethane surfactant [PQ14, PQ16 and PQ18] were synthesized by the reaction of alkyl bromoacetate (namely: tetradecyl-, hexadecyl- and octadecyl bromoacetate) as quaternizing agents and modified polyurethane contains tertiary amine species. Modified polyurethane was prepared by the reaction of toluene diisocyanate (TDI) and Triethanol amine mono mercaptoacetate. Grinding method is used to synthesize copper and nickel nanoparticles which stabilized by Cationic Thiol polyurethane surfactants. The chemical structures of the prepared surfactants were confirmed using elemental analysis, FTIR, UV and 1H-NMR spectroscopy. The molecular weight measurements of the prepared polymers showed that the segments of each polymer contain average 10 units of the urethane-Triethanol amine mercaptoacetate. The surface activities of the prepared surfactants including: surface tension (g), effectiveness (πcmc), concentration at micelle formation (CMC), efficiency (Pc20), maximum concentration at the interface (Gmax), average area occupied by each surfactant molecule at the interface at equilibrium (Amin) of surfactants solutions were established at 25°C. The surface tension and the critical micelle concentration values of the prepared surfactants were gradually decreased by the gradual increase of their alkyl chain length. Antimicrobial activity of the synthesized cationic surfactants and their nanostructure with copper and nickel nanoparticles were evaluated against pathogenic bacteria and fungi. The antimicrobial activity showed the enhancement in the antimicrobial activity of the synthesized cationic surfactants in the nanostructures form.
VL  - 6
IS  - 2
ER  -

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Author Information

Ibrahim Abdelsalam Sabbah

Chemistry Department, Faculty of Science, Al-Azhar University, Cairo, Egypt
Mostafa Eid Hendawy

Chemistry Department, Faculty of Science, Al-Azhar University, Cairo, Egypt
Mohammed Fahmy Zaky

Petrochemicals Department, Egyptian Petroleum Research Institute, Cairo, Egypt
Nabel Abdelmonem Negm

Petrochemicals Department, Egyptian Petroleum Research Institute, Cairo, Egypt

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Ibrahim Abdelsalam Sabbah, Mostafa Eid Hendawy, Mohammed Fahmy Zaky, Nabel Abdelmonem Negm. (2018). Synthesis, Surface Activities and Anti-Bacterial Activity of (Copper and Nickel) Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants. Modern Chemistry, 6(2), 23-34. https://doi.org/10.11648/j.mc.20180602.13

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ACS Style

Ibrahim Abdelsalam Sabbah; Mostafa Eid Hendawy; Mohammed Fahmy Zaky; Nabel Abdelmonem Negm. Synthesis, Surface Activities and Anti-Bacterial Activity of (Copper and Nickel) Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants. Mod. Chem. 2018, 6(2), 23-34. doi: 10.11648/j.mc.20180602.13

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AMA Style

Ibrahim Abdelsalam Sabbah, Mostafa Eid Hendawy, Mohammed Fahmy Zaky, Nabel Abdelmonem Negm. Synthesis, Surface Activities and Anti-Bacterial Activity of (Copper and Nickel) Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants. Mod Chem. 2018;6(2):23-34. doi: 10.11648/j.mc.20180602.13

Copy | Download

@article{10.11648/j.mc.20180602.13,
  author = {Ibrahim Abdelsalam Sabbah and Mostafa Eid Hendawy and Mohammed Fahmy Zaky and Nabel Abdelmonem Negm},
  title = {Synthesis, Surface Activities and Anti-Bacterial Activity of (Copper and Nickel) Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants},
  journal = {Modern Chemistry},
  volume = {6},
  number = {2},
  pages = {23-34},
  doi = {10.11648/j.mc.20180602.13},
  url = {https://doi.org/10.11648/j.mc.20180602.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.mc.20180602.13},
  abstract = {A series of cationic polyurethane surfactant [PQ14, PQ16 and PQ18] were synthesized by the reaction of alkyl bromoacetate (namely: tetradecyl-, hexadecyl- and octadecyl bromoacetate) as quaternizing agents and modified polyurethane contains tertiary amine species. Modified polyurethane was prepared by the reaction of toluene diisocyanate (TDI) and Triethanol amine mono mercaptoacetate. Grinding method is used to synthesize copper and nickel nanoparticles which stabilized by Cationic Thiol polyurethane surfactants. The chemical structures of the prepared surfactants were confirmed using elemental analysis, FTIR, UV and 1H-NMR spectroscopy. The molecular weight measurements of the prepared polymers showed that the segments of each polymer contain average 10 units of the urethane-Triethanol amine mercaptoacetate. The surface activities of the prepared surfactants including: surface tension (g), effectiveness (πcmc), concentration at micelle formation (CMC), efficiency (Pc20), maximum concentration at the interface (Gmax), average area occupied by each surfactant molecule at the interface at equilibrium (Amin) of surfactants solutions were established at 25°C. The surface tension and the critical micelle concentration values of the prepared surfactants were gradually decreased by the gradual increase of their alkyl chain length. Antimicrobial activity of the synthesized cationic surfactants and their nanostructure with copper and nickel nanoparticles were evaluated against pathogenic bacteria and fungi. The antimicrobial activity showed the enhancement in the antimicrobial activity of the synthesized cationic surfactants in the nanostructures form.},
 year = {2018}
}

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TY  - JOUR
T1  - Synthesis, Surface Activities and Anti-Bacterial Activity of (Copper and Nickel) Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants
AU  - Ibrahim Abdelsalam Sabbah
AU  - Mostafa Eid Hendawy
AU  - Mohammed Fahmy Zaky
AU  - Nabel Abdelmonem Negm
Y1  - 2018/07/27
PY  - 2018
N1  - https://doi.org/10.11648/j.mc.20180602.13
DO  - 10.11648/j.mc.20180602.13
T2  - Modern Chemistry
JF  - Modern Chemistry
JO  - Modern Chemistry
SP  - 23
EP  - 34
PB  - Science Publishing Group
SN  - 2329-180X
UR  - https://doi.org/10.11648/j.mc.20180602.13
AB  - A series of cationic polyurethane surfactant [PQ14, PQ16 and PQ18] were synthesized by the reaction of alkyl bromoacetate (namely: tetradecyl-, hexadecyl- and octadecyl bromoacetate) as quaternizing agents and modified polyurethane contains tertiary amine species. Modified polyurethane was prepared by the reaction of toluene diisocyanate (TDI) and Triethanol amine mono mercaptoacetate. Grinding method is used to synthesize copper and nickel nanoparticles which stabilized by Cationic Thiol polyurethane surfactants. The chemical structures of the prepared surfactants were confirmed using elemental analysis, FTIR, UV and 1H-NMR spectroscopy. The molecular weight measurements of the prepared polymers showed that the segments of each polymer contain average 10 units of the urethane-Triethanol amine mercaptoacetate. The surface activities of the prepared surfactants including: surface tension (g), effectiveness (πcmc), concentration at micelle formation (CMC), efficiency (Pc20), maximum concentration at the interface (Gmax), average area occupied by each surfactant molecule at the interface at equilibrium (Amin) of surfactants solutions were established at 25°C. The surface tension and the critical micelle concentration values of the prepared surfactants were gradually decreased by the gradual increase of their alkyl chain length. Antimicrobial activity of the synthesized cationic surfactants and their nanostructure with copper and nickel nanoparticles were evaluated against pathogenic bacteria and fungi. The antimicrobial activity showed the enhancement in the antimicrobial activity of the synthesized cationic surfactants in the nanostructures form.
VL  - 6
IS  - 2
ER  -

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