Interactions in Atomic and Ionic Liquids

Jean-Louis Bretonnet

doi:doi:10.11648/j.am.20200904.12

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Interactions in Atomic and Ionic Liquids

Jean-Louis Bretonnet

Published in Advances in Materials (Volume 9, Issue 4)

Received: 3 February 2020 Accepted: 9 July 2020 Published: 23 November 2020

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Abstract

This review seeks to describe, from first principles, the nature of the interaction forces in atomic and ionic liquids. The atoms and molecules made up of dipoles and multipoles interact with van der Waals forces, while the ionic systems are viewed as pseudoions interacting through effective forces depending on the electronic structure and the physical ionic arrangement. The interplay between these two aspects of materials is quite complex and forms the main subject of this review. As it will be shown, the two-component system of interacting electrons and ions can be reduced, in second order perturbation theory, to an effective one-component system made up of pseudoions acting under the influence of two-body, central, screened potentials. These potentials result from a weak interaction between the electrons and the ions, deduced from the pseudopotential theory. Once the interatomic forces are known, the atomic structure and the electronic transport properties can be determined by methods of classical mechanics and quantum mechanics. Besides, a large volume-dependent term in the free energy, independent of the ionic positions, which distinguishes the conducting liquids from the simple isolator liquids like argon, is indispensable for explaining the thermodynamical properties.

Published in	Advances in Materials (Volume 9, Issue 4)
DOI	10.11648/j.am.20200904.12
Page(s)	68-93
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

T-X Family, Exponentiated Exponential Distribution, Order Statistics, Shannon Entropy and Likelihood Ratio Test

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Jean-Louis Bretonnet. (2020). Interactions in Atomic and Ionic Liquids. Advances in Materials, 9(4), 68-93. https://doi.org/10.11648/j.am.20200904.12

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ACS Style

Jean-Louis Bretonnet. Interactions in Atomic and Ionic Liquids. Adv. Mater. 2020, 9(4), 68-93. doi: 10.11648/j.am.20200904.12

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Jean-Louis Bretonnet. Interactions in Atomic and Ionic Liquids. Adv Mater. 2020;9(4):68-93. doi: 10.11648/j.am.20200904.12

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@article{10.11648/j.am.20200904.12,
  author = {Jean-Louis Bretonnet},
  title = {Interactions in Atomic and Ionic Liquids},
  journal = {Advances in Materials},
  volume = {9},
  number = {4},
  pages = {68-93},
  doi = {10.11648/j.am.20200904.12},
  url = {https://doi.org/10.11648/j.am.20200904.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.am.20200904.12},
  abstract = {This review seeks to describe, from first principles, the nature of the interaction forces in atomic and ionic liquids. The atoms and molecules made up of dipoles and multipoles interact with van der Waals forces, while the ionic systems are viewed as pseudoions interacting through effective forces depending on the electronic structure and the physical ionic arrangement. The interplay between these two aspects of materials is quite complex and forms the main subject of this review. As it will be shown, the two-component system of interacting electrons and ions can be reduced, in second order perturbation theory, to an effective one-component system made up of pseudoions acting under the influence of two-body, central, screened potentials. These potentials result from a weak interaction between the electrons and the ions, deduced from the pseudopotential theory. Once the interatomic forces are known, the atomic structure and the electronic transport properties can be determined by methods of classical mechanics and quantum mechanics. Besides, a large volume-dependent term in the free energy, independent of the ionic positions, which distinguishes the conducting liquids from the simple isolator liquids like argon, is indispensable for explaining the thermodynamical properties.},
 year = {2020}
}

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TY  - JOUR
T1  - Interactions in Atomic and Ionic Liquids
AU  - Jean-Louis Bretonnet
Y1  - 2020/11/23
PY  - 2020
N1  - https://doi.org/10.11648/j.am.20200904.12
DO  - 10.11648/j.am.20200904.12
T2  - Advances in Materials
JF  - Advances in Materials
JO  - Advances in Materials
SP  - 68
EP  - 93
PB  - Science Publishing Group
SN  - 2327-252X
UR  - https://doi.org/10.11648/j.am.20200904.12
AB  - This review seeks to describe, from first principles, the nature of the interaction forces in atomic and ionic liquids. The atoms and molecules made up of dipoles and multipoles interact with van der Waals forces, while the ionic systems are viewed as pseudoions interacting through effective forces depending on the electronic structure and the physical ionic arrangement. The interplay between these two aspects of materials is quite complex and forms the main subject of this review. As it will be shown, the two-component system of interacting electrons and ions can be reduced, in second order perturbation theory, to an effective one-component system made up of pseudoions acting under the influence of two-body, central, screened potentials. These potentials result from a weak interaction between the electrons and the ions, deduced from the pseudopotential theory. Once the interatomic forces are known, the atomic structure and the electronic transport properties can be determined by methods of classical mechanics and quantum mechanics. Besides, a large volume-dependent term in the free energy, independent of the ionic positions, which distinguishes the conducting liquids from the simple isolator liquids like argon, is indispensable for explaining the thermodynamical properties.
VL  - 9
IS  - 4
ER  -

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Author Information

Jean-Louis Bretonnet

LCP-A2MC (EA 3469), University of Lorraine, Metz, France

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Jean-Louis Bretonnet. (2020). Interactions in Atomic and Ionic Liquids. Advances in Materials, 9(4), 68-93. https://doi.org/10.11648/j.am.20200904.12

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ACS Style

Jean-Louis Bretonnet. Interactions in Atomic and Ionic Liquids. Adv. Mater. 2020, 9(4), 68-93. doi: 10.11648/j.am.20200904.12

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AMA Style

Jean-Louis Bretonnet. Interactions in Atomic and Ionic Liquids. Adv Mater. 2020;9(4):68-93. doi: 10.11648/j.am.20200904.12

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@article{10.11648/j.am.20200904.12,
  author = {Jean-Louis Bretonnet},
  title = {Interactions in Atomic and Ionic Liquids},
  journal = {Advances in Materials},
  volume = {9},
  number = {4},
  pages = {68-93},
  doi = {10.11648/j.am.20200904.12},
  url = {https://doi.org/10.11648/j.am.20200904.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.am.20200904.12},
  abstract = {This review seeks to describe, from first principles, the nature of the interaction forces in atomic and ionic liquids. The atoms and molecules made up of dipoles and multipoles interact with van der Waals forces, while the ionic systems are viewed as pseudoions interacting through effective forces depending on the electronic structure and the physical ionic arrangement. The interplay between these two aspects of materials is quite complex and forms the main subject of this review. As it will be shown, the two-component system of interacting electrons and ions can be reduced, in second order perturbation theory, to an effective one-component system made up of pseudoions acting under the influence of two-body, central, screened potentials. These potentials result from a weak interaction between the electrons and the ions, deduced from the pseudopotential theory. Once the interatomic forces are known, the atomic structure and the electronic transport properties can be determined by methods of classical mechanics and quantum mechanics. Besides, a large volume-dependent term in the free energy, independent of the ionic positions, which distinguishes the conducting liquids from the simple isolator liquids like argon, is indispensable for explaining the thermodynamical properties.},
 year = {2020}
}

Copy | Download

TY  - JOUR
T1  - Interactions in Atomic and Ionic Liquids
AU  - Jean-Louis Bretonnet
Y1  - 2020/11/23
PY  - 2020
N1  - https://doi.org/10.11648/j.am.20200904.12
DO  - 10.11648/j.am.20200904.12
T2  - Advances in Materials
JF  - Advances in Materials
JO  - Advances in Materials
SP  - 68
EP  - 93
PB  - Science Publishing Group
SN  - 2327-252X
UR  - https://doi.org/10.11648/j.am.20200904.12
AB  - This review seeks to describe, from first principles, the nature of the interaction forces in atomic and ionic liquids. The atoms and molecules made up of dipoles and multipoles interact with van der Waals forces, while the ionic systems are viewed as pseudoions interacting through effective forces depending on the electronic structure and the physical ionic arrangement. The interplay between these two aspects of materials is quite complex and forms the main subject of this review. As it will be shown, the two-component system of interacting electrons and ions can be reduced, in second order perturbation theory, to an effective one-component system made up of pseudoions acting under the influence of two-body, central, screened potentials. These potentials result from a weak interaction between the electrons and the ions, deduced from the pseudopotential theory. Once the interatomic forces are known, the atomic structure and the electronic transport properties can be determined by methods of classical mechanics and quantum mechanics. Besides, a large volume-dependent term in the free energy, independent of the ionic positions, which distinguishes the conducting liquids from the simple isolator liquids like argon, is indispensable for explaining the thermodynamical properties.
VL  - 9
IS  - 4
ER  -

Copy | Download