Spectro-Magnetic and Antimicrobial Studies on some 3d Metal Complexes with Ethylenedianil of Ortho-Hydroxyphenylglyoxal

Ali Mohammed Yimer; T. Baraki; R. K. Upadhyay; Masood Akhtar

doi:doi:10.11648/j.ajac.20140201.14

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Spectro-Magnetic and Antimicrobial Studies on some 3d Metal Complexes with Ethylenedianil of Ortho-Hydroxyphenylglyoxal

Ali Mohammed Yimer, T. Baraki, R. K. Upadhyay, Masood Akhtar

Published in American Journal of Applied Chemistry (Volume 2, Issue 1)

Received: 19 February 2014 Published: 20 March 2014

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Abstract

The Cr(III), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes with a novel tetradentate ligand obtained by condensation of ethylenediamine with ortho-hydroxyphenylglyoxal have been synthesized and characterized by elemental analysis, molar conductance and magnetic susceptibility measurements, IR, UV-Visible and atomic absorption studies. The Cr(III), Fe(III) and Co(II) complexes possess six coordinate octahedral geometry whereas Ni(II), Cu(II) and Zn(II) complexes are square planar and tetrahedral respectively. Bactericidal and fungicidal activities of the compounds were evaluated in vitro by disc diffusion method. The perusal of antimicrobial activities of the compounds reveals that the complexes possess greater bactericidal and fungicidal activities against all the microbes in comparison to ligand which is due to their higher lipophilicity.

Published in	American Journal of Applied Chemistry (Volume 2, Issue 1)
DOI	10.11648/j.ajac.20140201.14
Page(s)	15-18
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Bactericidal and Fungicidal Activities, Ortho-Hydroxyphenylglyoxal, Thin-Layer Chromatography, Structural Geometry, Lipophilicity, Tetradentate Ligand

References

[1]	Z. H.Chohan, , A. Munawar and C. T. Supuran, 2001. Transition metal ion complexes of Schiff’s-bases synthesis, characterization and antibacterial properties. Metal-based drugs, 8: 137-143.
[2]	E. Canpolat, and M. Kaya, 2004. Studies on mononuclear chelates derived from substituted Schiff-base ligands (part 2): synthesis and characterization of a new 5-bromosalicyliden paminoacetophenone oxime and its complexes with Co(II), Ni(II), Cu(II) and Zn(II) J. Coord. Chem. 123.
[3]	Abdel-Rahman, L.H., El-Khatib, R.M., Nassr, L.A.E., and Abu-Dief, A. M., J. Mole. Struct., 2013, vol. 1040, p. 9.
[4]	R.K. Upadhyay, N.Agarwal, Nat. Acad. Sci.Letters, 14, 251 (1991).
[5]	R.K. Upadhyay, J. Indian Chem. Soc., 75,535 (1997).
[6]	M. B.Ferrari, , S. Capacchi, G. Pelosi, G. Reffo, P. Tarasconi, R .Albertini, S. Pinelli, P. Lunghi, 1999. Synthesis, structural characterization and biological activity of helicin thiosemicarbazone monohydrate and a Copper(II) complex of salicylaldehyde thiosemicarbazone Inorg. Chim. Acta, 286, 134-141.
[7]	R.K. Upadhyay, V. Sharma, V.P. Singh, J. Liq. Chromatogr., 5, 1141 (1982).
[8]	R.K. Upadhyay, A.K. Bajpai, K.Rathore, Chromatographia, 18,618 (1984).
[9]	D.L. Drew, A.L. Barry, R.O. Toole, J.C. Sherris, Appl. Environ. Microbial, 24,240 (1972).
[10]	W.J. Greay, Coordination Chemistry Reviews, Vol. 7, No.1, 81-122 (1971).
[11]	R.K. Upadhyay, A. Rani, Acta Chim. Hung., 126,195 (1989).
[12]	K.Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, Wiley-Interscience, N.Y., P. 295, 1970.
[13]	A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, the Netherlands, 1978.
[14]	G.H. Anuradha, A.V. Chandrapal; E-J. Chem., 8,421 (2011).
[15]	P.S. Badami, A.D. Kulkarni, S.A. Patil, J. Electrochem. Sci., 4, 717 (2019).
[16]	A.A. Elamari, A.N. El-Tajoury, S.A. I. Sharif, E-J. Chem., 8, 43 (2011).
[17]	A.A. Del Paggio, D.R. McMillin, Inorg. Chem. 22.691 (1983).
[18]	R.K. Upadhyay, Ph.D. Thesis, Meerut Univ, Meerut, 1972.
[19]	S. Chandra, D. Jain, A.K. Sharma, P. Sharma, Molecules, 14,174 (2009).

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APA Style

Ali Mohammed Yimer, T. Baraki, R. K. Upadhyay, Masood Akhtar. (2014). Spectro-Magnetic and Antimicrobial Studies on some 3d Metal Complexes with Ethylenedianil of Ortho-Hydroxyphenylglyoxal. American Journal of Applied Chemistry, 2(1), 15-18. https://doi.org/10.11648/j.ajac.20140201.14

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ACS Style

Ali Mohammed Yimer; T. Baraki; R. K. Upadhyay; Masood Akhtar. Spectro-Magnetic and Antimicrobial Studies on some 3d Metal Complexes with Ethylenedianil of Ortho-Hydroxyphenylglyoxal. Am. J. Appl. Chem. 2014, 2(1), 15-18. doi: 10.11648/j.ajac.20140201.14

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AMA Style

Ali Mohammed Yimer, T. Baraki, R. K. Upadhyay, Masood Akhtar. Spectro-Magnetic and Antimicrobial Studies on some 3d Metal Complexes with Ethylenedianil of Ortho-Hydroxyphenylglyoxal. Am J Appl Chem. 2014;2(1):15-18. doi: 10.11648/j.ajac.20140201.14

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@article{10.11648/j.ajac.20140201.14,
  author = {Ali Mohammed Yimer and T. Baraki and R. K. Upadhyay and Masood Akhtar},
  title = {Spectro-Magnetic and Antimicrobial Studies on some 3d Metal Complexes with Ethylenedianil of Ortho-Hydroxyphenylglyoxal},
  journal = {American Journal of Applied Chemistry},
  volume = {2},
  number = {1},
  pages = {15-18},
  doi = {10.11648/j.ajac.20140201.14},
  url = {https://doi.org/10.11648/j.ajac.20140201.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20140201.14},
  abstract = {The Cr(III), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes with  a novel tetradentate ligand obtained by condensation of ethylenediamine with ortho-hydroxyphenylglyoxal have been synthesized and characterized by elemental analysis, molar conductance and magnetic susceptibility measurements, IR, UV-Visible and atomic absorption studies. The Cr(III), Fe(III) and Co(II) complexes possess six coordinate octahedral geometry whereas Ni(II), Cu(II) and Zn(II) complexes are square planar and tetrahedral respectively. Bactericidal and fungicidal activities of the compounds were evaluated in vitro by disc diffusion method. The perusal of antimicrobial activities of the compounds reveals that the complexes possess greater bactericidal and fungicidal activities against all the microbes in comparison to ligand which is due to their higher lipophilicity.},
 year = {2014}
}

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TY  - JOUR
T1  - Spectro-Magnetic and Antimicrobial Studies on some 3d Metal Complexes with Ethylenedianil of Ortho-Hydroxyphenylglyoxal
AU  - Ali Mohammed Yimer
AU  - T. Baraki
AU  - R. K. Upadhyay
AU  - Masood Akhtar
Y1  - 2014/03/20
PY  - 2014
N1  - https://doi.org/10.11648/j.ajac.20140201.14
DO  - 10.11648/j.ajac.20140201.14
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 15
EP  - 18
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20140201.14
AB  - The Cr(III), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes with  a novel tetradentate ligand obtained by condensation of ethylenediamine with ortho-hydroxyphenylglyoxal have been synthesized and characterized by elemental analysis, molar conductance and magnetic susceptibility measurements, IR, UV-Visible and atomic absorption studies. The Cr(III), Fe(III) and Co(II) complexes possess six coordinate octahedral geometry whereas Ni(II), Cu(II) and Zn(II) complexes are square planar and tetrahedral respectively. Bactericidal and fungicidal activities of the compounds were evaluated in vitro by disc diffusion method. The perusal of antimicrobial activities of the compounds reveals that the complexes possess greater bactericidal and fungicidal activities against all the microbes in comparison to ligand which is due to their higher lipophilicity.
VL  - 2
IS  - 1
ER  -

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Author Information

Ali Mohammed Yimer

Department of Applied Chemistry, College of Natural and Computational Sciences, Arba Minch University (Ethiopia)
T. Baraki

Department of Chemistry, College of Natural and Computational Sciences, Hramaya University (Ethiopia)
R. K. Upadhyay

Department of Chemistry, College of Natural and Computational Sciences, Hramaya University (Ethiopia)
Masood Akhtar

Department of Applied Chemistry, College of Natural and Computational Sciences, Arba Minch University (Ethiopia)

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APA Style

Ali Mohammed Yimer, T. Baraki, R. K. Upadhyay, Masood Akhtar. (2014). Spectro-Magnetic and Antimicrobial Studies on some 3d Metal Complexes with Ethylenedianil of Ortho-Hydroxyphenylglyoxal. American Journal of Applied Chemistry, 2(1), 15-18. https://doi.org/10.11648/j.ajac.20140201.14

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ACS Style

Ali Mohammed Yimer; T. Baraki; R. K. Upadhyay; Masood Akhtar. Spectro-Magnetic and Antimicrobial Studies on some 3d Metal Complexes with Ethylenedianil of Ortho-Hydroxyphenylglyoxal. Am. J. Appl. Chem. 2014, 2(1), 15-18. doi: 10.11648/j.ajac.20140201.14

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AMA Style

Ali Mohammed Yimer, T. Baraki, R. K. Upadhyay, Masood Akhtar. Spectro-Magnetic and Antimicrobial Studies on some 3d Metal Complexes with Ethylenedianil of Ortho-Hydroxyphenylglyoxal. Am J Appl Chem. 2014;2(1):15-18. doi: 10.11648/j.ajac.20140201.14

Copy | Download

@article{10.11648/j.ajac.20140201.14,
  author = {Ali Mohammed Yimer and T. Baraki and R. K. Upadhyay and Masood Akhtar},
  title = {Spectro-Magnetic and Antimicrobial Studies on some 3d Metal Complexes with Ethylenedianil of Ortho-Hydroxyphenylglyoxal},
  journal = {American Journal of Applied Chemistry},
  volume = {2},
  number = {1},
  pages = {15-18},
  doi = {10.11648/j.ajac.20140201.14},
  url = {https://doi.org/10.11648/j.ajac.20140201.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20140201.14},
  abstract = {The Cr(III), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes with  a novel tetradentate ligand obtained by condensation of ethylenediamine with ortho-hydroxyphenylglyoxal have been synthesized and characterized by elemental analysis, molar conductance and magnetic susceptibility measurements, IR, UV-Visible and atomic absorption studies. The Cr(III), Fe(III) and Co(II) complexes possess six coordinate octahedral geometry whereas Ni(II), Cu(II) and Zn(II) complexes are square planar and tetrahedral respectively. Bactericidal and fungicidal activities of the compounds were evaluated in vitro by disc diffusion method. The perusal of antimicrobial activities of the compounds reveals that the complexes possess greater bactericidal and fungicidal activities against all the microbes in comparison to ligand which is due to their higher lipophilicity.},
 year = {2014}
}

Copy | Download

TY  - JOUR
T1  - Spectro-Magnetic and Antimicrobial Studies on some 3d Metal Complexes with Ethylenedianil of Ortho-Hydroxyphenylglyoxal
AU  - Ali Mohammed Yimer
AU  - T. Baraki
AU  - R. K. Upadhyay
AU  - Masood Akhtar
Y1  - 2014/03/20
PY  - 2014
N1  - https://doi.org/10.11648/j.ajac.20140201.14
DO  - 10.11648/j.ajac.20140201.14
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 15
EP  - 18
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20140201.14
AB  - The Cr(III), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes with  a novel tetradentate ligand obtained by condensation of ethylenediamine with ortho-hydroxyphenylglyoxal have been synthesized and characterized by elemental analysis, molar conductance and magnetic susceptibility measurements, IR, UV-Visible and atomic absorption studies. The Cr(III), Fe(III) and Co(II) complexes possess six coordinate octahedral geometry whereas Ni(II), Cu(II) and Zn(II) complexes are square planar and tetrahedral respectively. Bactericidal and fungicidal activities of the compounds were evaluated in vitro by disc diffusion method. The perusal of antimicrobial activities of the compounds reveals that the complexes possess greater bactericidal and fungicidal activities against all the microbes in comparison to ligand which is due to their higher lipophilicity.
VL  - 2
IS  - 1
ER  -

Copy | Download