The inhibiting effect of dithizone (Diphenylthiocarbazone) has been studied regarding the corrosion of 316 stainless steel in 20% w/w HCl at 35C. The effects of the inhibitor have been demonstrated using weight loss measurements. The increase of the inhibitor concentration leads to a decrease in the corrosion rate. This indicates a good adsorbability of dithizone (Diphenylthiocarbazone) on the metal surface. The value of ΔGad s has been calculated and dithizone has the potent to interact with 316 stainless steel through semi-physiosorption and/or semi-chemisorptions.
Published in | American Journal of Applied Chemistry (Volume 2, Issue 1) |
DOI | 10.11648/j.ajac.20140201.11 |
Page(s) | 1-5 |
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Copyright © The Author(s), 2014. Published by Science Publishing Group |
Corrosion Inhibitor, 316 Stainless Steel, HCl, Dithizone
[1] | N. Tantawy., Evaluation of New Cationic Surfactant as Corrosion Inhibitor for Carbon Steel in a metal Working Fluid" The Annals of University "Dunărea de JOS " of Galaţi Fascicle VIII, p. (2005) 112-114. |
[2] | Ayo S. Afolabi. Synergistic Inhibition of Potassium Chromate and Sodium Nitrite on Mild Steel in Chloride and Sulphide Media. Leonardo Electronic Journal of Practices and Technologies,p.(2007) 144. |
[3] | Ashish Kumar Singh, M.A. Quraishi. Effect of 2,20 benzothiazolyl disulfide on the corrosion of mild steel in acid media. Corrosion Science 51 (2009) 2752–2760 |
[4] | I. Ahmad, M. Rahuma and A. Knish, The Nitrogenous Corrosion Inhibitors Used in Petroleum Production International Journal of Pharmaceutical and Chemical Sciences Vol. 3 (1) Jan-Mar (2014) 255-259 |
[5] | Libin Tang, Guannan Mu, Guangheng Liu. The effect of neutral red on thecorrosioninhibitionof cold rolled steelin 1.0 M hydrochloric acid. Corrosion Science 45 (2003) 2251–2262 |
[6] | Moulay A. EL Mhammedi and Abdelilah Chtaini, Investigation of the Inhibitive Effect of Pyrazolo [3, 4-b] Pyridine on Corrosion of Stainless Steel in 1 M HCl Solutions. Leonardo Electronic Journal of Practices and Technologies, p.(2007) 37-43. |
[7] | F.H. Assaf; M.Abou-Krish; A.S.El-Shahawy; M.Th.Makhlouf and HalaSoudy,. The synergistic inhibitive effect and the thermodynamic parameters of 2 (2- hydroxylstyryl) pyridinium-N- ethyl iodide and some metal cations on the acid corrosion of low-carbon steel.International Journal of Electrochemical Science ,Vol (2007) 2, 169 – 178. |
[8] | Atul Kumar,. Corrosion Inhibition of Mild Steel in Hydrochloric Acid by Sodium Lauryl Sulfate (SLS). E-Journal of Chemistry Vol. (2008) 5 , p. 275-276. |
[9] | Leila Herrag; Balkheir Hammouti; Abdelouahad Aouniti; Sghir El Kadiri and Rachid Touzani,. Effect of Diaminoalkane Derivatives on Steel Corrosion in HCL Media .Acta Chim., p.(2007) 419–422. |
[10] | Ehteram A. Noor." Temperature Effects on the Corrosion Inhibition of Mild Steel in Acidic Solutions by Aqueous Extract of Fenugreek Leaves. International Journal of Electrochemical Science, Vol. (2007) 2,p. 998 – 1013. |
[11] | Ehteram A. Noor; Aisha H. and Al-Moubaraki.. Corrosion Behavior of Mild Steel in Hydrochloric Acid Solutions "International Journal of Electrochemical Science,Vol. (2008) 3, p. 817. |
[12] | Khadija Hnini; Salah Fadel; Molay A. EL Mhammedi; Abdelilah Chtaini and El Mostapha Rakib, The Inhibition Effect of Heterocyclic Compounds towards the Corrosion of Iron in Phosphoric Media" Leonardo Electronic Journal of Practices and Technologies, p.(2008) 4. |
[13] | Adriana Samide; Ion Bibicu; Mircea Rogalski; and Mircea Preda, A study of The Corrosion Inhibition of Carbon-Steel in Dilluted Ammonia Media Using 2-Mercapto-Benzothiazol" Acta Chim., p.(2004) 128. |
[14] | A. Popova and M. Christov,. Inhibitive Properties of Quaternary Ammonium Bromides of N-containing Hetero cycles on Acid Mild Steel Corrosion.Journal of the University of Chemical Technology and Metallurgy, 43,p.(2008). 39. |
[15] | S. D. Shetty; P. Shetty and H. V. S. Nayak,2006." The inhibition action of N-furfuryl-N'-phenyl thiourea on the corrosion of mild steel in acid media"J. Serb. Chem. Soc., 71, p. 1080. |
[16] | V. R. Saliyan and Airody V. Adhikari,. Inhibition of corrosion of mild steel in acid media by N′-benzylidene-3-(quinolin-4-ylthio) propanohydrazide. Bull. Mater. Sci., Vol. (2008) 31, p. 704-708 |
[17] | A. Musa, A. Kadhum, A. Mohamad, A. Daud, M. Takriff, and S, Kamarudin, Corrosion inhibition of mild steel in sulphuric acid by 4,4-dimethyloxazolidine-2-thione, Corrosion science, 51(10), (2009) 2393-2399. |
[18] | Deana Wahyuningrum; Sadijah Achmad; Yana M. Syah; Buchari; Bunbun Bundjali and Bambang Ariwahjoedi,. The Correlation between Structure and Corrosion Inhibition Activity of 4,5-Diphenyl-1-vinylimidazole Derivative Compounds towards Mild Steel in 1% NaCl Solution" International Journal of Electrochemical Science, Vol. 3,p.(2008) 160-162. |
[19] | M. Bouklah and B. Hammouti,. Thermodynamin Characterisation of Steel Corrosion for The Corrosion Inhibition of Steel in Sulphuric Acid Solutions by Artemisia. Portugaliae Electrochimical Acta, 24,p. (2006) 463. |
[20] | M. Rahuma, M. EL-Sabbah, and I. Hamad, Effect of Serine and Methionine on Electrochemical Behavior of the Corrosion of Mild Steel in Aqueous Solutions ISRN Corrosion (2013), ID 895120, 7 pages |
[21] | H. Zarrok1, A. Zarrouk, R. Salghi, M. Assouag, B. Hammouti, H. Oudda1, S. Boukhris, S. S. Al Deyab and I. Warad, Inhibitive properties and thermodynamic characterization of quinoxaline derivative on carbon steel corrosion in acidic medium Der Pharmacia Lettre, 5 (2) (2013), 43-53 |
[22] | Eyad M. Nawafleh, Tareq T. Bataineh, Muna K. Irshedat, Mahmoud A. Al-Qudah and Sultan T. Abu Orabi Inhibition of Aluminum Corrosion by Salvia Judica Extract Res. J. Chem. Sci Vol. 3(8), (2013). 68-72, August. |
APA Style
Mohamed Nuri Rahuma, Fadwa Mahamed Al-Sonosy, Atega Mohamed Al-Frjany. (2014). Corrosion Inhibition of 316 Stainless Steel in 20%(W/W) HCl Solution using Dithizone. American Journal of Applied Chemistry, 2(1), 1-5. https://doi.org/10.11648/j.ajac.20140201.11
ACS Style
Mohamed Nuri Rahuma; Fadwa Mahamed Al-Sonosy; Atega Mohamed Al-Frjany. Corrosion Inhibition of 316 Stainless Steel in 20%(W/W) HCl Solution using Dithizone. Am. J. Appl. Chem. 2014, 2(1), 1-5. doi: 10.11648/j.ajac.20140201.11
AMA Style
Mohamed Nuri Rahuma, Fadwa Mahamed Al-Sonosy, Atega Mohamed Al-Frjany. Corrosion Inhibition of 316 Stainless Steel in 20%(W/W) HCl Solution using Dithizone. Am J Appl Chem. 2014;2(1):1-5. doi: 10.11648/j.ajac.20140201.11
@article{10.11648/j.ajac.20140201.11, author = {Mohamed Nuri Rahuma and Fadwa Mahamed Al-Sonosy and Atega Mohamed Al-Frjany}, title = {Corrosion Inhibition of 316 Stainless Steel in 20%(W/W) HCl Solution using Dithizone}, journal = {American Journal of Applied Chemistry}, volume = {2}, number = {1}, pages = {1-5}, doi = {10.11648/j.ajac.20140201.11}, url = {https://doi.org/10.11648/j.ajac.20140201.11}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20140201.11}, abstract = {The inhibiting effect of dithizone (Diphenylthiocarbazone) has been studied regarding the corrosion of 316 stainless steel in 20% w/w HCl at 35C. The effects of the inhibitor have been demonstrated using weight loss measurements. The increase of the inhibitor concentration leads to a decrease in the corrosion rate. This indicates a good adsorbability of dithizone (Diphenylthiocarbazone) on the metal surface. The value of ΔGad s has been calculated and dithizone has the potent to interact with 316 stainless steel through semi-physiosorption and/or semi-chemisorptions.}, year = {2014} }
TY - JOUR T1 - Corrosion Inhibition of 316 Stainless Steel in 20%(W/W) HCl Solution using Dithizone AU - Mohamed Nuri Rahuma AU - Fadwa Mahamed Al-Sonosy AU - Atega Mohamed Al-Frjany Y1 - 2014/01/30 PY - 2014 N1 - https://doi.org/10.11648/j.ajac.20140201.11 DO - 10.11648/j.ajac.20140201.11 T2 - American Journal of Applied Chemistry JF - American Journal of Applied Chemistry JO - American Journal of Applied Chemistry SP - 1 EP - 5 PB - Science Publishing Group SN - 2330-8745 UR - https://doi.org/10.11648/j.ajac.20140201.11 AB - The inhibiting effect of dithizone (Diphenylthiocarbazone) has been studied regarding the corrosion of 316 stainless steel in 20% w/w HCl at 35C. The effects of the inhibitor have been demonstrated using weight loss measurements. The increase of the inhibitor concentration leads to a decrease in the corrosion rate. This indicates a good adsorbability of dithizone (Diphenylthiocarbazone) on the metal surface. The value of ΔGad s has been calculated and dithizone has the potent to interact with 316 stainless steel through semi-physiosorption and/or semi-chemisorptions. VL - 2 IS - 1 ER -