Preparation, Characterization and Theoretical Study of Metal Complexes Derived from N5 Acyclic Ligand, American Journal of Applied Chemistry, Science Publishing Group

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Preparation, Characterization and Theoretical Study of Metal Complexes Derived from N5 Acyclic Ligand

Mahmoud Najim Al-jibouri, Omar Hamad Shehab AL-Obaidi

Published in American Journal of Applied Chemistry (Volume 1, Issue 3)

Received: 16 June 2013 Published: 30 August 2013

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Abstract

The complexes of a new pentadentate acyclic ligand derived from 1,2-diamino benzen and 2,6-diacetylpyridine ,with vanadium(IV), Mn(II) and Fe(III )have been synthesized and characterized on the bases of their elemental analysis, GS mass for ligand, conductivity, magnetic moments in addition to spectral data of IR and UV-Visible Spectra. Metal to ligand ratio in all complexes has been found to be (1:1). The polydentate ligand behaves as N5 system upon linkage with Fe(III) and Mn(II) ions. All the complexes have been assigned as octahedral geometries of general formula [MnL]Cl, [FeLCl]Cl2 and [VOL]SO. A theoretical treatment of the formation of complexes in the gas phase was studied; this was done using the HYPERCHEM-6 program for the Molecular mechanics and Semi-empirical calculations.

Published in	American Journal of Applied Chemistry (Volume 1, Issue 3)
DOI	10.11648/j.ajac.20130103.11
Page(s)	37-42
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Preparation, Characterization, Theoretical Study, Metal Complexes, Acyclic Ligand

References

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Mahmoud Najim Al-jibouri, Omar Hamad Shehab AL-Obaidi. (2013). Preparation, Characterization and Theoretical Study of Metal Complexes Derived from N5 Acyclic Ligand. American Journal of Applied Chemistry, 1(3), 37-42. https://doi.org/10.11648/j.ajac.20130103.11

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ACS Style

Mahmoud Najim Al-jibouri; Omar Hamad Shehab AL-Obaidi. Preparation, Characterization and Theoretical Study of Metal Complexes Derived from N5 Acyclic Ligand. Am. J. Appl. Chem. 2013, 1(3), 37-42. doi: 10.11648/j.ajac.20130103.11

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AMA Style

Mahmoud Najim Al-jibouri, Omar Hamad Shehab AL-Obaidi. Preparation, Characterization and Theoretical Study of Metal Complexes Derived from N5 Acyclic Ligand. Am J Appl Chem. 2013;1(3):37-42. doi: 10.11648/j.ajac.20130103.11

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@article{10.11648/j.ajac.20130103.11,
  author = {Mahmoud Najim Al-jibouri and Omar Hamad Shehab AL-Obaidi},
  title = {Preparation, Characterization and Theoretical Study of Metal Complexes Derived from N5 Acyclic Ligand},
  journal = {American Journal of Applied Chemistry},
  volume = {1},
  number = {3},
  pages = {37-42},
  doi = {10.11648/j.ajac.20130103.11},
  url = {https://doi.org/10.11648/j.ajac.20130103.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20130103.11},
  abstract = {The complexes of a new pentadentate acyclic ligand derived from 1,2-diamino benzen and 2,6-diacetylpyridine ,with vanadium(IV), Mn(II) and Fe(III )have been synthesized and characterized on the bases of their elemental analysis, GS mass for ligand, conductivity, magnetic moments in addition to spectral data of IR and UV-Visible Spectra. Metal to ligand ratio in all complexes has been found to be (1:1). The polydentate ligand behaves as N5 system upon linkage with Fe(III) and Mn(II) ions. All the complexes have been assigned as octahedral geometries of general formula [MnL]Cl, [FeLCl]Cl2 and [VOL]SO. A theoretical treatment of the formation of complexes in the gas phase was studied; this was done using the HYPERCHEM-6 program for the Molecular mechanics and Semi-empirical calculations.},
 year = {2013}
}

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TY  - JOUR
T1  - Preparation, Characterization and Theoretical Study of Metal Complexes Derived from N5 Acyclic Ligand
AU  - Mahmoud Najim Al-jibouri
AU  - Omar Hamad Shehab AL-Obaidi
Y1  - 2013/08/30
PY  - 2013
N1  - https://doi.org/10.11648/j.ajac.20130103.11
DO  - 10.11648/j.ajac.20130103.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 37
EP  - 42
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20130103.11
AB  - The complexes of a new pentadentate acyclic ligand derived from 1,2-diamino benzen and 2,6-diacetylpyridine ,with vanadium(IV), Mn(II) and Fe(III )have been synthesized and characterized on the bases of their elemental analysis, GS mass for ligand, conductivity, magnetic moments in addition to spectral data of IR and UV-Visible Spectra. Metal to ligand ratio in all complexes has been found to be (1:1). The polydentate ligand behaves as N5 system upon linkage with Fe(III) and Mn(II) ions. All the complexes have been assigned as octahedral geometries of general formula [MnL]Cl, [FeLCl]Cl2 and [VOL]SO. A theoretical treatment of the formation of complexes in the gas phase was studied; this was done using the HYPERCHEM-6 program for the Molecular mechanics and Semi-empirical calculations.
VL  - 1
IS  - 3
ER  -

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Author Information

Mahmoud Najim Al-jibouri

Chemistry Department, College of Science ,Al-Mustansrya University
Omar Hamad Shehab AL-Obaidi

Chemistry Department, Women Education College, Al-Anbar University

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APA Style

Mahmoud Najim Al-jibouri, Omar Hamad Shehab AL-Obaidi. (2013). Preparation, Characterization and Theoretical Study of Metal Complexes Derived from N5 Acyclic Ligand. American Journal of Applied Chemistry, 1(3), 37-42. https://doi.org/10.11648/j.ajac.20130103.11

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ACS Style

Mahmoud Najim Al-jibouri; Omar Hamad Shehab AL-Obaidi. Preparation, Characterization and Theoretical Study of Metal Complexes Derived from N5 Acyclic Ligand. Am. J. Appl. Chem. 2013, 1(3), 37-42. doi: 10.11648/j.ajac.20130103.11

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AMA Style

Mahmoud Najim Al-jibouri, Omar Hamad Shehab AL-Obaidi. Preparation, Characterization and Theoretical Study of Metal Complexes Derived from N5 Acyclic Ligand. Am J Appl Chem. 2013;1(3):37-42. doi: 10.11648/j.ajac.20130103.11

Copy | Download

@article{10.11648/j.ajac.20130103.11,
  author = {Mahmoud Najim Al-jibouri and Omar Hamad Shehab AL-Obaidi},
  title = {Preparation, Characterization and Theoretical Study of Metal Complexes Derived from N5 Acyclic Ligand},
  journal = {American Journal of Applied Chemistry},
  volume = {1},
  number = {3},
  pages = {37-42},
  doi = {10.11648/j.ajac.20130103.11},
  url = {https://doi.org/10.11648/j.ajac.20130103.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20130103.11},
  abstract = {The complexes of a new pentadentate acyclic ligand derived from 1,2-diamino benzen and 2,6-diacetylpyridine ,with vanadium(IV), Mn(II) and Fe(III )have been synthesized and characterized on the bases of their elemental analysis, GS mass for ligand, conductivity, magnetic moments in addition to spectral data of IR and UV-Visible Spectra. Metal to ligand ratio in all complexes has been found to be (1:1). The polydentate ligand behaves as N5 system upon linkage with Fe(III) and Mn(II) ions. All the complexes have been assigned as octahedral geometries of general formula [MnL]Cl, [FeLCl]Cl2 and [VOL]SO. A theoretical treatment of the formation of complexes in the gas phase was studied; this was done using the HYPERCHEM-6 program for the Molecular mechanics and Semi-empirical calculations.},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - Preparation, Characterization and Theoretical Study of Metal Complexes Derived from N5 Acyclic Ligand
AU  - Mahmoud Najim Al-jibouri
AU  - Omar Hamad Shehab AL-Obaidi
Y1  - 2013/08/30
PY  - 2013
N1  - https://doi.org/10.11648/j.ajac.20130103.11
DO  - 10.11648/j.ajac.20130103.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 37
EP  - 42
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20130103.11
AB  - The complexes of a new pentadentate acyclic ligand derived from 1,2-diamino benzen and 2,6-diacetylpyridine ,with vanadium(IV), Mn(II) and Fe(III )have been synthesized and characterized on the bases of their elemental analysis, GS mass for ligand, conductivity, magnetic moments in addition to spectral data of IR and UV-Visible Spectra. Metal to ligand ratio in all complexes has been found to be (1:1). The polydentate ligand behaves as N5 system upon linkage with Fe(III) and Mn(II) ions. All the complexes have been assigned as octahedral geometries of general formula [MnL]Cl, [FeLCl]Cl2 and [VOL]SO. A theoretical treatment of the formation of complexes in the gas phase was studied; this was done using the HYPERCHEM-6 program for the Molecular mechanics and Semi-empirical calculations.
VL  - 1
IS  - 3
ER  -

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